Sulfuryl fluoride

Sulfuryl fluoride
Names
IUPAC name
Sulfuryl fluoride
Other names
Sulfonyl fluoride; Sulfur dioxide difluoride; Sulphuryl fluoride; Sulfuryl difluoride; Vikane
Identifiers
2699-79-8 N
3D model (Jmol) Interactive image
ChEBI CHEBI:39287 YesY
ChemSpider 16647 YesY
ECHA InfoCard 100.018.437
PubChem 17607
Properties
SO2F2
Molar mass 102.06 g/mol
Appearance colourless gas
Odor odorless[1]
Density 4.172 g/L (gas), 1.632 g/mL (liquid under compressed gas at 0 °C)
Melting point −124.7 °C (−192.5 °F; 148.5 K)
Boiling point −55.4 °C (−67.7 °F; 217.8 K)
0.2% (0°C)[1]
Solubility in other solvents SO2
Vapor pressure 15.8 atm (21°C)[1]
Structure
tetrahedral
Hazards
Main hazards toxic
NFPA 704
Flammability code 0: Will not burn. E.g., water Health code 3: Short exposure could cause serious temporary or residual injury. E.g., chlorine gas Reactivity code 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g., calcium Special hazards (white): no codeNFPA 704 four-colored diamond
0
3
1
Lethal dose or concentration (LD, LC):
991 ppm (rat, 4 hr)[2]
1200 ppm (mouse, 1 hr)
5000 ppm (rabbit, 1 hr)[2]
US health exposure limits (NIOSH):
PEL (Permissible)
 TWA 5 ppm (20 mg/m3)[1]
REL (Recommended)
 TWA 5 ppm (20 mg/m3) ST 10 ppm (40 mg/m3)[1]
IDLH (Immediate danger)
 200 ppm[1]
Related compounds
Related compounds
 SO2Cl2,
SO2ClF,
SF6,
SO3
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YesYN ?)
Infobox references

Sulfuryl fluoride (also spelled sulphuryl fluoride) is the inorganic compound with the formula SO2F2. This easily condensed gas has properties more similar to sulfur hexafluoride than sulfuryl chloride, being resistant to hydrolysis even up to 150 °C.[3]

It is widely used as a structural insecticide fumigant to treat termites and other pests. Inhalation is hazardous and potentially fatal to humans and animals.[4]

Structure, preparation, reactions

The molecule is tetrahedral with C2v symmetry. The S-O distance is 140.5 pm, S-F is 153.0 pm. As predicted by VSEPR, the O-S-O angle is more open than the F-S-F angle, 124° and 97°, respectively.[3]

One synthesis begins with the preparation of potassium fluorosulfite:[5]

SO2 + KF → KSO2F

This salt is then chlorinated to give sulfuryl chloride fluoride:

KSO2F + Cl2 → SO2ClF + KCl

Further heating at 180 °C of potassium fluorosulfite with the sulfuryl chloride fluoride gives the desired product:[6]

SO2ClF + KSO2F → SO2F2 + KCl + SO2

Heating metal fluorosulfonate salts also gives this molecule:[3]

Ba(OSO2F)2 → BaSO4 + SO2F2

It can be prepared by direct reaction of fluorine with sulfur dioxide:

SO2 + F2 → SO2F2

Sulfuryl fluoride is unreactive toward molten sodium metal.[3] Similarly it is slow to hydrolyze, but eventually converts to sulfur trioxide.[7][8]

Use as a fumigant

Originally developed by the Dow Chemical Company, sulfuryl fluoride is in widespread use as a structural fumigant insecticide to control drywood termites, particularly in warm-weather portions of the southwestern and southeastern United States and in Hawaii. Less commonly, it can also be used to control rodents, powderpost beetles, deathwatch beetles, bark beetles, and bedbugs. Its use has increased as a replacement for methyl bromide, which was phased out because of harm to the ozone layer. It is an alternative to the use of phosphine, which is acutely toxic.[9]

Fumigation methodology

During application, the building is enclosed in what "experts" describe incorrectly as "a tight tent" and filled with the gas for a period of time, usually at least 16–18 hours, sometimes as long as 72 hours. The building must then be ventilated, generally for at least 6 hours, before occupants can return. California regulations are such that the tent will be on for three to five days, which includes ventilation. In the US, sulfuryl fluoride must be transported in a vehicle marked with "Inhalation Hazard 2" placards.[10][11] Most states require a license or certification for the individual applying the fumigant.

The concentration is continuously monitored and maintained at the specified level using electronic equipment. Possible leakages are also checked by low range electronic detectors. Reentry to the home is allowed when the concentration level is at or below 5 ppm.[4] Sulfuryl fluoride is colorless, and odorless however, during the fumigation process, a warning agent called chloropicrin is first released into the building to ensure that no occupants remain. Tent fumigation is the most effective treatment for the extermination of known and unknown infestations of wood-destroying insects. Heat is the only other approved method for whole structure treatment for termites in California.[12] Sulfuryl fluoride provides no protection from future infestations, although heavy re-infestation can take several years since drywood termites have slower growing colonies than ground termites.

U.S. Perspective

Sulfuryl fluoride is marketed in the U.S. by three manufacturers, under four different brand names. Vikane (Dow) (EPA Reg. No. 62719- 4-ZA) has been commercially available since the early 1960s, with Zythor (marketed by competitor Ensystex of North Carolina) (EPA Reg. No. 81824- 1-AA) being more recently introduced gradually as its use is approved by individual states (in Florida circa 2004, but not in California until October 2006, for example). Sulfuryl fluoride has been marketed as a post-harvest fumigant for dry fruits, nuts, and grains under the trade name ProFume (U.S. EPA Reg. No. 62719- 376-AA).[13] Most recently Drexel Chemical Company has registered Master Fume (EPA Reg. No. 19713-596-AA) for the structural market, competing against Vikane and Zythor.[14]

Health Hazards

Inhalation of sulfuryl fluoride is hazardous and may result in respiratory irritation, pulmonary edema, nausea, abdominal pain, central nervous system, depression, numbness in the extremities, muscle twitching, seizures, and death .[15][16][17] These high exposures occurred when people entered into structures illegally during fumigation or after insufficient aeration. Epidemiological studies showed that fumigation workers who used sulfuryl fluoride showed neurological effects, which included reduced performance on cognitive tests and pattern memory tests, and reduced olfactory function.[4]

Case studies

In 2016, a 24-year-old man who allegedly entered an apartment that was being fumigated in Fremont, California to commit a burglary was exposed to Sulfuryl Fluoride and Chloropicrin and died shortly thereafter. According to a police officer, he experienced labored breathing and was sweating before he collapsed just a few steps from the first floor window of the apartment he allegedly robbed.[18]

In 2015 a 10-year-old boy suffered severe brain damage and lost function of his left arm and leg after his home was treated with sulfuryl fluoride and insufficiently aerated, prompting a criminal investigation by the Department of Justice and the Florida Department of Agricultural and Consumer Services.[19]

In 1987 an elderly couple was exposed to sulfuryl fluoride in their house already cleared for reentry.[4] While the fumigation company opened windows and doors, and aerated the house with fans, sulfuryl fluoride level was not measured. It was not detected when the air was sampled 12 days after aeration. The couple experienced weakness, nausea and shortness of breath that evening. The man suffered a seizure and died the following day. His wife’s condition got worse with pulmonary edema, and she died after a cardiovascular arrest 6 days later.

Greenhouse gas

Based on the first high frequency, high precision, in situ atmospheric and archived air measurements, sulfuryl fluoride has an atmospheric lifetime of 30–40 years,[7] much longer than the 5 years earlier estimated.[20]

Sulfuryl fluoride has been reported to be a greenhouse gas which is about 4000-5000 times more efficient in trapping infrared radiation (per kg) than carbon dioxide (per kg).[7][21][22] It is important to note, however, that amounts of sulfuryl fluoride released into the atmosphere (about 2000 metric tons per yr[7]) are far lower than the amounts of CO2 released by hydrocarbon-burning vehicles, industry, and other processes (about 30 billion metric tons per year). The most important loss process of sulfuryl fluoride is dissolution of atmospheric sulfuryl fluoride in the ocean followed by hydrolysis.

References

  1. 1 2 3 4 5 6 "NIOSH Pocket Guide to Chemical Hazards #0581". National Institute for Occupational Safety and Health (NIOSH).
  2. 1 2 "Sulfuryl fluoride". Immediately Dangerous to Life and Health. National Institute for Occupational Safety and Health (NIOSH).
  3. 1 2 3 4 Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001. ISBN 0-12-352651-5.
  4. 1 2 3 4 "SULFURYL FLUORIDE (Vikane®) RISK CHARACTERIZATION DOCUMENT" (PDF). State of California. Retrieved 16 July 2012.
  5. ↑ Seel, F. "Potassium Fluorosulfite" Inorganic Syntheses 1967, IX, pages 113-115. doi:10.1002/9780470132401.ch29.
  6. ↑ Seel, F. "Sulfuryl Chloride Fluoride and Sulfuryl Fluoride" Inorganic Syntheses 1967, vol. IX, pages 111-113. doi:10.1002/9780470132401.ch28
  7. 1 2 3 4 Mühle, J., J. Huang, R.F. Weiss, R.G. Prinn, B.R. Miller, P.K. Salameh, C.M. Harth, P.J. Fraser, L.W. Porter, B.R. Greally, S. O'Doherty, and P.G. Simmonds, Sulfuryl Fluoride in the Global Atmosphere, Journal of Geophysical Research, 114, D05306, doi:10.1029/2008JD011162, 2009
  8. ↑ Cady, G.H., and S. Misra, Hydrolysis of Sulfuryl Fluoride, Inorganic Chemistry, 13 (4), 837-841, 1974. doi:10.1021/ic50134a016
  9. ↑ Bell, C. H. "Fumigation in the 21st century" "Crop Protection, 2000, 19, 563-569. ISSN 0261-2194. AN 2000:895590
  10. ↑ "Code of Federal Regulations, Title 49, Part 172.101". US Government Publishing Office (GPO). 5 September 2015. Retrieved 5 September 2015.
  11. ↑ "Electronic Code of Federal Regulations, 49 CFR part 172.540, POISON GAS placard". US Government Publishing Office (GPO), Electronic Code of Federal Regulations. 5 September 2015. Retrieved 5 September 2015.
  12. ↑ Termites Fact Sheet
  13. ↑ http://www.dowagro.com/profume/index.htm
  14. ↑ Output Reporting
  15. ↑ Schneir A, Clark RF, Kene M, Betten D (November 2008). "Systemic fluoride poisoning and death from inhalational exposure to sulfuryl fluoride". Clin Toxicol (Phila). 46 (9): 850–4. doi:10.1080/15563650801938662. PMID 18608259.
  16. ↑ Centers for Disease Control (CDC) (Sep 18, 1987). "Fatalities resulting from sulfuryl fluoride exposure after home fumigation--Virginia". MMWR Morb Mortal Wkly Rep. 36 (36): 602–4, 609–11. PMID 3114607.
  17. ↑ Scheuerman EH (1986). "Suicide by exposure to sulfuryl fluoride". J Forensic Sci. 31 (3): 1154–8. PMID 3734735.
  18. ↑ "Fremont Burglary Suspect Who Entered Fumigated Home Dies". Retrieved 2016-05-24.
  19. ↑ Ganim, Sara (5 September 2015). "10-year-old hospitalized after termite fumigation". Cable News Network (CNN). Retrieved 5 September 2015. Sulfuryl fluoride, a gas fumigant, was the pesticide used to fumigate, sources told CNN.
  20. ↑ KEMI, SULFURYL FLUORIDE (PT8), Competent Authority Report, Document III-A7, Ecotoxicological Profile Including Environmental Fate and Behaviour, Swedish Chemicals Agency, Sweden, 2005.
  21. ↑ Papadimitriou, V.C., R.W. Portmann, D.W. Fahey, J. Mühle, R.F. Weiss, and J.B. Burkholder, Experimental and Theoretical Study of the Atmospheric Chemistry and Global Warming Potential of SO2F2, Journal of Physical Chemistry A, 112 (49), 12657-12666, doi:10.1021/jp806368u, 2008.
  22. ↑ Sulbaek Andersen, M.P., D.R. Blake, F.S. Rowland, M.D. Hurley, and T.J. Wallington, Atmospheric Chemistry of Sulfuryl Fluoride: Reaction with OH Radicals, Cl Atoms and O3, Atmospheric Lifetime, IR Spectrum, and Global Warming Potential, Environmental Science & Technology, doi:10.1021/es802439f, 2009.
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