Oxygen-free copper

The CuOFP capsule used as overpack for spent nuclear fuel disposal in the KBS-3 concept (Swedish version)

Oxygen-free copper (OFC) or Oxygen-free high thermal conductivity (OFHC) copper is a group of wrought high conductivity copper alloys that have been electrolytically refined to reduce the level of oxygen to .001% or below.[1][2]


Oxygen-free copper is typically specified according to the ASTM/UNS database.[3] The UNS database includes many different compositions of high conductivity electrical copper. Of these three are widely used and two are considered oxygen-free.

Oxygen-free high thermal conductivity

Oxygen-free high thermal conductivity (OFHC) copper is widely used in cryogenics. OFHC is produced by the direct conversion of selected refined cathodes and castings under carefully controlled conditions to prevent contamination of the pure oxygen-free metal during processing. The method of producing OFHC copper ensures extra high grade of metal with a copper content of 99.99%. With so small a content of extraneous elements, the inherent properties of elemental copper are brought forth to a high degree. These characteristics are high ductility, high electrical and thermal conductivity, high impact strength, good creep resistance, ease of welding, and low relative volatility under high vacuum.[4]


Conductivity is generally specified relative to the 1913 International Annealed Copper Standard of 58 MS/m. Advances in the refining process now yield OF and ETP copper that can meet or exceed 101% of this standard. (Ultra-pure copper has a conductivity of 58.65 MS/m, 102.75% IACS.) Note that OF and ETP coppers have identical conductivity requirements.[5]

Oxygen plays a beneficial role for improving copper conductivity. During the copper smelting process, oxygen is deliberately injected into the melt to scavenge impurities that would otherwise degrade conductivity.[6]

There are advanced refining processes such as the Czochralski process than can be used to reduce impurity levels to below the C10100 specification by reducing copper grain density.[7][8][9][10] At this time, there are currently no UNS/ASTM classifications for these specialty coppers and the IACS conductivity of these coppers is not readily available.

Industrial applications

For industrial applications, oxygen-free copper is valued more for its chemical purity than its electrical conductivity. OF/OFE grade copper is used in plasma deposition (sputtering) processes, including the manufacture of semiconductors and superconductor components, as well as in high vacuum devices such as particle accelerators. In any of these applications, the release of oxygen or other impurities can cause undesirable chemical reactions with other materials in the local environment.[11]

Use in home audio

The high-end speaker wire industry markets oxygen-free copper as having enhanced conductivity or other electrical properties that are supposedly advantageous to audio signal transmission. However, conductivity specifications for common C11000 Electrolytic-Tough-Pitch (ETP) and higher-cost C10200 Oxygen-Free (OF) coppers are identical.[12] Much more expensive C10100, a highly refined copper with silver impurities removed and oxygen reduced to 0.0005%, has only a one percent higher conductivity—insignificant in audio applications.[12] OFC is nevertheless sold for both audio and video signals in audio playback systems and home cinema.[12]

Oxygen-free phosphorus-containing copper

High electrical conductivity coppers are distinct from coppers deoxidized by the addition of phosphorus in the smelting process. Oxygen-free phosphorus-containing copper (CuOFP) is typically used for structural and thermal applications where the copper material will be subject to temperatures high enough to cause hydrogen embrittlement or more exactly steam embrittlement. Examples include welding/brazing rods and heat exchanger tubing.[13]

Indeed, copper alloys which contain oxygen as an impurity (in the form of residual oxides present in the metal matrix) can be embrittled if exposed to hot hydrogen. The hydrogen diffuses through the copper and reacts with inclusions of Cu2O, forming H2O (water), which then forms pressurized water steam bubbles at the grain boundaries. This process can cause the grains to be forced away from each other, and is known as steam embrittlement (because steam is produced, not because exposure to steam causes the problem).

CuOFP has been selected as corrosion resistant material for the overpack of spent nuclear fuel in the KBS-3 concept developed in Sweden and Finland to dispose high-level radioactive waste in crystalline rock formations.

See also


  1. "Innovations: Introduction to Copper: Types of Copper". Copper.org. 2010-08-25. Retrieved 2011-07-05.
  2. "ASTM Standard Designation for Wrought and Cast Copper and Copper Alloys". Resources: Standards & Properties. Copper.org. 2010-08-25. Retrieved 2011-07-05.
  3. "ASTM Standard Designation for Wrought and Cast Copper and Copper Alloys: Introduction". Copper.org. 2010-08-25. Retrieved 2011-07-05.
  4. "Oxygen-Free Copper". Anchorbronze.com. Retrieved 2011-07-05.
  5. "Innovations in Copper: Electrical and Metallurgy of Copper: High Copper Alloys". Copper.org. 2010-08-25. Retrieved 2011-07-05.
  6. "Innovations : The Metallurgy of Copper Wire". Copper.org. 2010-08-25. Retrieved 2011-07-05.
  7. Tanner, B. K. (1972). "The perfection of Czochralski grown copper single crystals". Journal of Crystal Growth. 16 (1): 86–87. doi:10.1016/0022-0248(72)90094-2.
  8. Akita, H.; Sampar, D. S.; Fiore, N. F. (1973). "Substructure control by solidification control in Cu crystals". Metallurgical Transactions. 4 (6): 15935–15937. doi:10.1007/BF02668013.
  9. Kato, Masanori (1995). "The production of ultrahigh-purity copper for advanced applications". JOM. 47 (12): 44–46. doi:10.1007/BF03221340.
  10. Isohara. "Characteristics of Our 9N-Cu(99.9999999%)" (PDF). ACROTEC High Purity Metals. Retrieved 21 May 2016.
  11. http://www.hitachi-cable.co.jp/catalog/CE100.pdf
  12. 1 2 3 Russell, Roger. "Speaker Wire – A History". Retrieved August 25, 2011.
  13. "High Conductivity Copper for Electrical Engineering". Copper Development Association. 2016-02-01. Retrieved 2016-02-11.
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