Phenol formaldehyde resin
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Phenol formaldehyde resins (PF) or phenolic resins are synthetic polymers obtained by the reaction of phenol or substituted phenol with formaldehyde. Used as the basis for Bakelite, PFs were the first commercial synthetic resins (plastics). They have been widely used for the production of molded products including billiard balls, laboratory countertops, and as coatings and adhesives. They were at one time the primary material used for the production of circuit boards but have been largely replaced with epoxy resins and fiberglass cloth, as with fire-resistant FR-4 circuit board materials.
There are two main production methods. One reacts phenol and formaldehyde directly to produce a thermosetting network polymer, while the other restricts the formaldehyde to produce a prepolymer known as novolac which can be moulded and then cured with the addition of more formaldehyde and heat. There are many variations in both production and input materials that are used to produce a wide variety of resins for special purposes.
Formation and structure
Phenol-formaldehyde resins, as a group, are formed by a step-growth polymerization reaction that can be either acid- or base-catalysed. Since formaldehyde exists predominantly in solution as a dynamic equilibrium of methylene glycol oligomers, the concentration of the reactive form of formaldehyde depends on temperature and pH.
Phenol reacts with formaldehyde at the ortho and para sites (sites 2, 4 and 6) allowing up to 3 units of formaldehyde to attach to the ring. The initial reaction in all cases involves the formation of a hydroxymethyl phenol:
- HOC6H5 + CH2O → HOC6H4CH2OH
The hydroxymethyl group is capable of reacting with either another free ortho or para site, or with another hydroxymethyl group. The first reaction gives a methylene bridge, and the second forms an ether bridge:
- HOC6H4CH2OH + HOC6H5 → (HOC6H4)2CH2 + H2O
- 2 HOC6H4CH2OH → (HOC6H4CH2)2O + H2O
The diphenol (HOC6H4)2CH2 (sometimes called a "dimer") is called bisphenol F, which is an important monomer in the production of epoxy resins. Bisphenol-F can further link generating tri- and tetra-and higher phenol oligomers.
Novolacs are phenol-formaldehyde resins with a formaldehyde to phenol molar ratio of less than one. The polymerization is brought to completion using acid-catalysis such as oxalic acid, hydrochloric acid or sulfonate acids. The phenol units are mainly linked by methylene and/or ether groups. Novolacs are commonly used as photoresists. See also photolithography. The molecular weights are in the low thousands, corresponding to about 10–20 phenol units.
Hexamethylenetetramine or "hexamine" is a hardener added to crosslink novolac. At a temperature >90 °C, it forms methylene and dimethylene amino bridges.
Base-catalysed phenol-formaldehyde resins are made with a formaldehyde to phenol ratio of greater than one (usually around 1.5). These resins are called resoles. Phenol, formaldehyde, water and catalyst are mixed in the desired amount, depending on the resin to be formed, and are then heated. The first part of the reaction, at around 70 °C, forms a thick reddish-brown tacky material, which is rich in hydroxymethyl and benzylic ether groups.
The rate of the base-catalysed reaction initially increases with pH, and reaches a maximum at about pH = 10. The reactive species is the phenoxide anion (C6H5O−) formed by deprotonation of phenol. The negative charge is delocalised over the aromatic ring, activating sites 2, 4 and 6, which then react with the formaldehyde.
Being thermosets, hydroxymethyl phenols will crosslink on heating to around 120 °C to form methylene and methyl ether bridges through the elimination of water molecules. At this point the resin is a 3-dimensional network, which is typical of polymerised phenolic resins. The high crosslinking gives this type of phenolic resin its hardness, good thermal stability, and chemical imperviousness. Resols are referred to as "one step" resins as they cure without a cross linker unlike novolacs, a "two step" resin.
Resols are major polymeric resin materials widely used for gluing and bonding building materials. Exterior plywood, oriented strand boards (OSB), engineered laminated composite lumber (LCL) are typical applications.
Crosslinking and the formaldehyde/phenol ratio
When the molar ratio of formaldehyde:phenol reaches one, in theory every phenol is linked together via methylene bridges, generating one single molecule, and the system is entirely crosslinked. This is why novolacs (F:P <1) do not harden without the addition of a crosslinking agent, and why resols with the formula F:P >1 will.
Phenolic resins are found in myriad industrial products. Phenolic laminates are made by impregnating one or more layers of a base material such as paper, fiberglass or cotton with phenolic resin and laminating the resin-saturated base material under heat and pressure. The resin fully polymerizes (cures) during this process. The base material choice depends on the intended application of the finished product. Paper phenolics are used in manufacturing electrical components such as punch-through boards, in household laminates, and in paper composite panels. Glass phenolics are particularly well suited for use in the high speed bearing market. Phenolic micro-balloons are used for density control. Snooker balls as well as balls from many table-based ball games are also made from phenol formaldehyde resin. The binding agent in normal (organic) brake pads, brake shoes and clutch disks are phenolic resin. Synthetic resin bonded paper, made from phenolic resin and paper, is used to make countertops.
Phenolic resins are also used for making exterior plywood commonly known as WBP (Weather & boil proof) Plywood because phenolic resins have no melting point but only a decomposing point in the temperature zone of 220 degree Celsius and above.
Sometimes people select phenolic resin parts because their coefficient of thermal expansion closely matches that of the aluminum used for other parts of a system, as in early computer systems and Duramold.
The Dutch forger Han van Meegeren mixed phenol formaldehyde with his oil paints before baking the finished canvas in order to fake the drying out of the paint over the centuries.
- Bakelite is made from phenolic resin and wood flour.
- Novotext is cotton fibre-reinforced phenolic, using randomly oriented fibres.
- Oasis is "an open-celled phenolic foam that readily absorbs water and is used as a base for flower arrangements."
- Maritex Aquarius is a very high performance bearing material made using novolac resin, fibre reinforcement and added lubricants for momentary dry run situations. It is also used dry at slow speeds and high pressures, showing very low wear rates of shaft or bearing.
- Paxolin is a resin bonded paper product long used as a base material for printed circuit boards, although it is being replaced by fiberglass composites in many applications.
- Tufnol is paper-reinforced phenolic resin product available as sheet and rods with many engineering applications due to its high compliance and resistance to oils and solvents.
Phenol-formaldehyde is degraded by the white rot fungus Phanerochaete chrysosporium
- A. Gardziella, L.A. Pilato, A. Knop, Phenolic Resins: Chemistry, Applications, Standardization, Safety and Ecology, 2nd edition, Springer, 2000
- Wolfgang Hesse "Phenolic Resins" in Ullmann's Encyclopedia of Industrial Chemistry, 2002, Wiley-VCH, Weinheim. doi:10.1002/14356007.a19_371.
- J. G. Ferguson, W. E. Grutzner, D. C. Koehler, R. S. Skinner, M. T. Skubiak, and D. H. Wetherell. "No. 1 ESS Apparatus and Equipment". The Bell System Technical Journal. 1964. p. 2417.
- "Smithers Oasis Resource Center". Web.archive.org. Archived from the original on 7 April 2008. Retrieved 2010-10-21.
- Gusse AC; Miller PD; Volk TJ (July 2006). "White-rot fungi demonstrate first biodegradation of phenolic resin". Environmental Science and Technology. PMID 16856735.
No longer available from the previously linked source.