| Name | Role | Number of
caps | Number of
goals | First cap | Opponent | Venue |
| Franco Jara | Forward | 4 | 1 | 26 January 2010 |  Costa Rica | Estadio Ingeniero Hilario Sánchez, San Juan, Argentina |
| Adrián Gabbarini | Goalkeeper | 3 | 0 | 5 May 2010 |  Haiti | El Coloso del Ruca Quimey, Cutral Có, Argentina |
| Javier Pastore | Midfielder | 14 | 1 | 24 May 2010 |  Canada | Estadio Monumental, Buenos Aires, Argentina |
| Nicolás Pareja | Defender | 1 | 0 | 17 November 2010 |  Brazil | Khalifa International Stadium, Doha, Qatar |
| Marcos Rojo | Defender | 17 | 0 | 9 February 2011 |  Portugal | Stade de Genève, Carouge, Switzerland |
| Lucas Biglia | Midfielder | 10 | 0 | 9 February 2011 | Portugal | Stade de Genève, Carouge, Switzerland |
| Juan Manuel Martínez | Forward | 4 | 1 | 9 February 2011 | Portugal | Stade de Genève, Carouge, Switzerland |
| Javier García | Goalkeeper | 1 | 0 | 16 March 2011 |  Venezuela | Estadio Monumental, Buenos Aires, Argentina |
| Agustín Marchesín | Goalkeeper | 1 | 0 | 16 March 2011 | Venezuela | Estadio Monumental, Buenos Aires, Argentina |
| Ivan Pillud | Defender | 5 | 0 | 16 March 2011 | Venezuela | Estadio Monumental, Buenos Aires, Argentina |
| Lisandro López | Defender | 4 | 0 | 16 March 2011 | Venezuela | Estadio Monumental, Buenos Aires, Argentina |
| Jonathan Maidana | Defender | 2 | 0 | 16 March 2011 | Venezuela | Estadio Monumental, Buenos Aires, Argentina |
| Gastón Díaz | Defender | 1 | 0 | 16 March 2011 | Venezuela | Estadio Monumental, Buenos Aires, Argentina |
| Cristian Chávez | Midfielder | 3 | 1 | 16 March 2011 | Venezuela | Estadio Monumental, Buenos Aires, Argentina |
| Diego Valeri | Midfielder | 3 | 0 | 16 March 2011 | Venezuela | Estadio Monumental, Buenos Aires, Argentina |
| Ariel Rojas | Midfielder | 3 | 0 | 16 March 2011 | Venezuela | Estadio Monumental, Buenos Aires, Argentina |
| Claudio Yacob | Midfielder | 2 | 1 | 16 March 2011 | Venezuela | Estadio Monumental, Buenos Aires, Argentina |
| Luciano Aued | Midfielder | 2 | 1 | 16 March 2011 | Venezuela | Estadio Monumental, Buenos Aires, Argentina |
| Mauricio Sperdutti | Midfielder | 2 | 0 | 16 March 2011 | Venezuela | Estadio Monumental, Buenos Aires, Argentina |
| Maxi Moralez | Midfielder | 1 | 0 | 16 March 2011 | Venezuela | Estadio Monumental, Buenos Aires, Argentina |
| Pablo Mouche | Forward | 5 | 2 | 16 March 2011 | Venezuela | Estadio Monumental, Buenos Aires, Argentina |
| Federico Fernández | Defender | 18 | 2 | 20 April 2011 |  Ecuador | Estadio José Maria Minella, Mar del Plata, Argentina |
| Ismael Quílez | Defender | 2 | 0 | 20 April 2011 | Ecuador | Estadio José Maria Minella, Mar del Plata, Argentina |
| Julián Velázquez | Defender | 1 | 0 | 20 April 2011 | Ecuador | Estadio José Maria Minella, Mar del Plata, Argentina |
| Lucas Viatri | Forward | 3 | 0 | 20 April 2011 | Ecuador | Estadio José Maria Minella, Mar del Plata, Argentina |
| Érik Lamela | Midfielder | 2 | 0 | 25 May 2011 |  Paraguay | Estadio Centenario, Resistencia, Argentina |
| Diego Morales | Midfielder | 1 | 0 | 25 May 2011 | Paraguay | Estadio Centenario, Resistencia, Argentina |
| Mateo Musacchio | Defender | 2 | 0 | 1 June 2011 |  Nigeria | Abuja National Stadium, Abuja, Nigeria |
| Federico Fazio | Defender | 2 | 0 | 1 June 2011 | Nigeria | Abuja National Stadium, Abuja, Nigeria |
| Tino Costa | Midfielder | 2 | 0 | 1 June 2011 | Nigeria | Abuja National Stadium, Abuja, Nigeria |
| Ariel Cabral | Midfielder | 2 | 0 | 1 June 2011 | Nigeria | Abuja National Stadium, Abuja, Nigeria |
| Nicolás Bertolo | Midfielder | 2 | 0 | 1 June 2011 | Nigeria | Abuja National Stadium, Abuja, Nigeria |
| Mauro Formica | Midfielder | 1 | 0 | 5 June 2011 |  Poland | Polish Army Stadium, Warsaw, Poland |
| Pablo Piatti | Midfielder | 1 | 0 | 5 June 2011 | Poland | Polish Army Stadium, Warsaw, Poland |
| Marco Ruben | Forward | 1 | 1 | 5 June 2011 | Poland | Polish Army Stadium, Warsaw, Poland |
| Jonathan Cristaldo | Forward | 1 | 0 | 5 June 2011 | Poland | Polish Army Stadium, Warsaw, Poland |
| Ricky Álvarez | Midfielfer | 3 | 0 | 2 September 2011 | Venezuela | Salt Lake Stadium, Calcutta, India |
| Agustín Orion | Goalkeeper | 3 | 0 | 14 September 2011 | Brazil | Estadio Mario Alberto Kempes, Córdoba, Argentina |
| Leandro Desábato | Defender | 5 | 0 | 14 September 2011 | Brazil | Estadio Mario Alberto Kempes, Córdoba, Argentina |
| Christian Cellay | Defender | 2 | 0 | 14 September 2011 | Brazil | Estadio Mario Alberto Kempes, Córdoba, Argentina |
| Augusto Fernández | Midfielder | 4 | 1 | 14 September 2011 | Brazil | Estadio Mario Alberto Kempes, Córdoba, Argentina |
| Héctor Canteros | Midfielder | 2 | 0 | 14 September 2011 | Brazil | Estadio Mario Alberto Kempes, Córdoba, Argentina |
| Cristian Chavez | Forward | 1 | 0 | 14 September 2011 | Brazil | Estadio Mario Alberto Kempes, Córdoba, Argentina |
| Emmanuel Gigliotti | Forward | 1 | 0 | 14 September 2011 | Brazil | Estadio Mario Alberto Kempes, Córdoba, Argentina |
| Walter Montillo | Midfielder | 6 | 0 | 28 September 2011 | Brazil | Estádio Mangueirão, Belem, Brazil |
| Hugo Campagnaro | Defender | 10 | 0 | 29 February 2012 |  Switzerland | Stade de Suisse, Bern, Switzerland |
| Gino Peruzzi | Defender | 4 | 0 | 19 September 2012 | Brazil | Estadio Serra Dourada, Goiânia, Brazil |
| Santiago Vergini | Defender | 1 | 0 | 19 September 2012 | Brazil | Estadio Serra Dourada, Goiânia, Brazil |
| Hernán Barcos | Forward | 4 | 0 | 19 September 2012 | Brazil | Estadio Serra Dourada, Goiânia, Brazil |
| Rogelio Funes Mori | Forward | 1 | 0 | 19 September 2012 | Brazil | Estadio Serra Dourada, Goiânia, Brazil |
| Franco Di Santo | Forward | 3 | 0 | 14 October 2012 |  Saudi Arabia | King Fahd International Stadium, Riyad, Saudi Arabia |
| Oscar Ahumada | Midfielder | 1 | 0 | 21 November 2012 | Brazil | Estadio Alberto J. Armando, Buenos Aires, Argentina |
| Francisco Cerro | Midfielder | 1 | 0 | 21 November 2012 | Brazil | Estadio Alberto J. Armando, Buenos Aires, Argentina |
| Ignacio Scocco | Forward | 1 | 2 | 21 November 2012 | Brazil | Estadio Alberto J. Armando, Buenos Aires, Argentina |
| José María Basanta | Defender | 3 | 0 | 26 March 2013 |  Bolivia | Estadio Hernando Siles, La Paz, Bolivia |
Chile